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You don't need to enable VoLTE. Insert the Jio (VoLTE enabled) in any slot. By default VoLTE will be active. If it is not, you can change the network preferences from Network option in settings.
Praful P V P
I will recommend you Samsung Galaxy S9. It comes with 5.8-inch Super AMOLED display which features a screen resolution of 1,440 x 2,960 pixels. Under the hood, there are two quad-core processors (2.3 GHz M2 Mongoose and 1.7GHz Cortex A53) and those are seated upon Samsung Exynos 9 Octa 9810 chipset with 4GB of RAM. A primary camera having 12MP resolution and front camera of 8MP helps to capture high-resolution images. The smartphone derives its energy from a 3,000mAh Li-ion battery inclusive of fast charging support.
It has all the elements which the user desires from a top brand like Samsung.
You can also check the complete comparison here: Apple iPhone X vs Samsung Galaxy S9
I will recommend you with OnePlus 6. The device comes with a 6.28-inch screen with Optic AMOLED display technology and a resolution of 1,080 x 2,280 pixels.
The smartphone features a single front-facing camera with a 16MP resolution to promise quality selfies and video calling. At the rear, the smartphone features an excellent dual-camera setup with 16MP and 20MP resolution, which are assisted by dual-LED flash. It is powered by a 2.8GHz Kryo 385 octa-core processor and is assisted by a massive 6GB RAM for flawless performance. The OnePlus 6 is a perfect smartphone, loaded with every feature you would expect your smartphone to have.
You can also check the complete comparison here: OnePlus 6 vs iPhone X