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Samsung S7 Edge is a better overall choice as it comes with a better processor, battery, Screen resolution and it is a gives a much better overall smartphone experience as it provided great camera quality and overall performance.
Let us analyze the two devices in detail.
Samsung S7 Edge has a 2.3 GHz OctaCore, Exynos 8890 processor, much faster than that of 1.8 GHz Snapdragon 450 Processor in Vivo V7 plus as discussed further in the benchmark scores of both the devices:-
Antutu Benchmark for Samsung S7 edge is 137,414 and Vivo V7+is 58,000 (Higher the better).
Geekbench (Single Core score) for Samsung S7 edge is 1751 and Vivo V7+ is not yet specified. (Higher the better).
Samsung S7 edge comes with a better 3600 mAh battery than 3225 mAh battery in Vivo V7 plus. With better battery capacity it provides a better on-screen of 4-5 Hours which helps to use various apps for a longer time period.
Samsung S7 Edge provides a better Super AMOLED display with screen resolution of (1440*2560 px). This brilliant display provides more pixels which means that there it gives a crisper picture and video quality.
Samsung S7 edge offers NFC technology which is one of the latest technology for transferring files and it always a plus point to have the latest technology like these.
Though Vivo V7 Plus comes with 16 megapixels (MP) camera resolution than Samsung S7 Edge (12MP).But the camera performance of both the devices is quite brilliant.
In this case, Samsung S7 Edge offers a great front and rear camera performance.
The only thing that keeps Vivo V7 plus in the competition is a better 64 GB storage capacity.
Samsung S7 edge is a clear winner here in terms of overall specs and performanceYou can check the detailed comparison using the following link Samsung S7 Edge vs ViVo V7 Plus