No, Nokia 220 4G will not support Jio sim as it is not capable of supporting 4G Indian bands. It will only be supporting 2G bands,
For complete product specification check: Nokia 220 4G
No, the Nokia 220 4G does not support VoLTE and despite being a 4G device, the phone does not support Indian 4G bands.
So, the user won't be able to use 4G and VoLTE anyway.
Check Full Device Specifications Nokia 220 4G